Okay, after about 6 to 8 hours of leaving Poser10 open, it accepted my request to add my daz library. About two hours after that I still couldn't see the library, but in the search tab I could search for items and after about thirty minutes or so it would find it, thus allowing me to add it to a scene. Although it did take quite some time before it actually made it to the scene.

Still can't see the library though...